Title : Charge migration fragmentation in the negative ion mode of cyclopentenone and cyclopentanone intermediates in the biosynthesis of jasmonates.

Pub. Date : 2020 Apr 30

PMID : 31734961






1 Functional Relationships(s)
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1 CONCLUSIONS: CID of 12-OPDA and 12-OPEA generates cyclopentanone enolate anions at m/z 165 by charge-driven hydride transfer as a common mechanism and by bond cleavage between C-7 and C-8 of the carboxyl side chains with either gain or loss of a hydrogen atom. 12-oxophytodienoic acid complement C7 Homo sapiens