Title : Reduction reactions of water soluble cyano-cobalt(III)-porphyrins: metal versus ligand centered processes.

Pub. Date : 1990 Jun

PMID : 2380707






2 Functional Relationships(s)
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1 On the other hand, under radiolytic conditions, [(CN)2CoIIITMPyP]- is reduced on the porphyrin macrocycle by one electron to give the CoIII pi-radical anion, which disproportionates into the initial complex and the two-electron ring reduced CoIII phlorin. Porphyrins mitochondrially encoded cytochrome c oxidase III Homo sapiens
2 On the other hand, under radiolytic conditions, [(CN)2CoIIITMPyP]- is reduced on the porphyrin macrocycle by one electron to give the CoIII pi-radical anion, which disproportionates into the initial complex and the two-electron ring reduced CoIII phlorin. Porphyrins mitochondrially encoded cytochrome c oxidase III Homo sapiens