Title : Metal-Free Temperature-Controlled Regiodivergent Borylative Cyclizations of Enynes: BCl3 -Promoted Skeletal Rearrangement.

Pub. Date : 2022 May 5

PMID : 35510716






1 Functional Relationships(s)
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1 Based on DFT calculations, a mechanism for these novel transformations has been proposed, which involves an uncommon skeletal rearrangement, including migration of a methyl group and alkyne fragmentation, unprecedented in BCl3-promoted cyclization reactions. Alkynes BCL3 transcription coactivator Homo sapiens