Title : Oxygen-Atom Defect Formation in Polyoxovanadate Clusters via Proton-Coupled Electron Transfer.

Pub. Date : 2022 Mar 23

PMID : 35275632






1 Functional Relationships(s)
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1 Kinetic investigations reveal that H-atom transfer to the metal oxide surface occurs through concerted proton-electron transfer, resulting in the formation of a transient VIII-OH2 moiety that, upon displacement of the water ligand with an acetonitrile molecule, forms the oxygen-deficient polyoxovanadate-alkoxide cluster. alkoxide cytochrome c oxidase subunit 8A Homo sapiens