Title : Low-Fe(III) driven UV/Air process for enhanced recovery of heavy metals from EDTA complexed system.

Pub. Date : 2020 Mar 15

PMID : 31865128






4 Functional Relationships(s)
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1 The inside mechanism of the LFUA process includes: 1) displacement of HMIs from HMI-EDTA complexes by Fe(III); 2) direct photolysis of Fe(III)-EDTA through a ligand-to-metal charge transition reaction (LMCT) and indirect photolysis of EDTA by HO2 /O2 -. Iron heme oxygenase 2 Homo sapiens
2 Fe(II) formed during the LMCT reaction of Fe(III)-EDTA was oxidized back to Fe(III) by O2 and HO2 , and the reformed Fe(III) was then recombined with EDTA to sustains the LMCT reaction. Iron heme oxygenase 2 Homo sapiens
3 Fe(II) formed during the LMCT reaction of Fe(III)-EDTA was oxidized back to Fe(III) by O2 and HO2 , and the reformed Fe(III) was then recombined with EDTA to sustains the LMCT reaction. Iron heme oxygenase 2 Homo sapiens
4 Fe(II) formed during the LMCT reaction of Fe(III)-EDTA was oxidized back to Fe(III) by O2 and HO2 , and the reformed Fe(III) was then recombined with EDTA to sustains the LMCT reaction. Iron heme oxygenase 2 Homo sapiens