Title : Theoretical Probe to the Mechanism of Pt-Catalyzed C-H Acylation Reaction: Possible Pathways for the Acylation Reaction of a Platinacycle.

Pub. Date : 2020 Jan 6

PMID : 31834795






1 Functional Relationships(s)
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Compound Name
Protein Name
Organism
1 (2) B undergoes 1,2-acyl migration from the platinum to the cyclometalated carbon through a three-membered platinacycle transition state to give Pt-arene eta2-complex E with an energy barrier of 14.0 kcal/mol. Platinum DNA polymerase iota Homo sapiens