Title : Efficient and Selective Conversion of Phosphine-Protected (MAu8)2+ (M = Pd, Pt) Superatoms to Thiolate-Protected (MAu12)6+ or Alkynyl-Protected (MAu12)4+ Superatoms via Hydride Doping.

Pub. Date : 2019 Oct 9

PMID : 31525916






1 Functional Relationships(s)
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1 An efficient and selective method was developed for the synthesis of ubiquitous clusters, MAu24L18 (M = Pd or Pt; L = thiolates or al-kynyls), by the reaction of Au(I)L oligomers with quasi-spherical superatoms [HMAu8(PPh3)8]+ activated by hydride doping. Platinum caveolin 1 Homo sapiens