Title : Snapshots of a Migrating H-Atom: Characterization of a Reactive Iron(III) Indenide Hydride and its Nearly Isoenergetic Ring-Protonated Iron(I) Isomer.

Pub. Date : 2019 Oct 21

PMID : 31465624






1 Functional Relationships(s)
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1 We report the characterization of an S= 1 / 2 iron pi-complex, [Fe(eta6 -IndH)(depe)]+ (Ind=Indenide (C9 H7 - ), depe=1,2-bis(diethylphosphino)ethane), which results via C-H elimination from a transient FeIII hydride, [Fe(eta3 :eta2 -Ind)(depe)H]+ . Iron DNA polymerase iota Homo sapiens