Title : Iron and Cobalt Diazoalkane Complexes Supported by β-Diketiminate Ligands: A Synthetic, Spectroscopic, and Computational Investigation.

Pub. Date : 2018 May 21

PMID : 29741884






1 Functional Relationships(s)
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1 A formally zerovalent cobalt complex has different structures depending on whether potassium binds; potassium binding gives transfer of two electrons into the eta2-diazoalkane, but the removal of the potassium with crown ether leads to a form with only one electron transferred into an eta1-diazoalkane. Cobalt DNA polymerase iota Homo sapiens