Title : Selective Transformation of CO2 to CO at a Single Nickel Center.

Pub. Date : 2018 May 15

PMID : 29634236






1 Functional Relationships(s)
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1 Two isolated nickel-CO2 adducts, (PPMeP)Ni(eta2-CO2-kappa C) (2) and {Na(12-C-4)2}{(PNP)Ni(eta1-CO2-kappa C)} (7), clearly demonstrate that the geometry of the nickel ion is crucial in the binding of CO2 and its level of activation. Nickel DNA polymerase iota Homo sapiens