Title : Competition versus Cooperation in Catalytic Hydrogelators for anti-Selective Mannich Reaction.

Pub. Date : 2017 Jul 21

PMID : 28513914






2 Functional Relationships(s)
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Compound Name
Protein Name
Organism
1 Proline and acid groups appended to catalytic fibers of two self-sorting hydrogelators compete for the Mannich reaction between aniline, benzaldehyde, and cyclohexanone to give low overall selectivity (anti/syn 77:23). Proline synemin Homo sapiens
2 In a sol-gel system of the same molecules, on the other hand, the soluble acid appended molecules tend to cooperate with the fibers of proline-appended catalyst to give improved selectivity (anti/syn 95:5). Proline synemin Homo sapiens