Title : Controlled Flexible Coordination in Tripodal Iron(II) Phosphane Complexes: Effects on Reactivity.

Pub. Date : 2016 Feb 1

PMID : 26751622






1 Functional Relationships(s)
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1 Whereas reaction of Triphos(Si) and FeX2 (X = Cl, Br) exclusively afforded (Triphos(Si))FeX2 with a kappa(2)-coordinated ligand, the homologous C-derived Fe complexes show rapid conversion in solution to afford [(Triphos)Fe(CH3CN)3][Fe2Cl6] or [(Triphos)Fe(CH3CN)3][FeBr4], respectively. Fe2Cl6 stabilin 2 Homo sapiens