Title : Lewis Acid Coupled Electron Transfer of Metal-Oxygen Intermediates.

Pub. Date : 2015 Dec 1

PMID : 26404482






2 Functional Relationships(s)
Download
Sentence
Compound Name
Protein Name
Organism
1 The mechanisms of the oxidative C H bond cleavage of toluene derivatives, sulfoxidation of thioanisole derivatives, and epoxidation of styrene derivatives by mononuclear nonheme iron(IV)-oxo complexes in the presence of triflic acid (HOTf) and Sc(OTf)3 have been unified as rate-determining electron transfer coupled with binding of Lewis acids (HOTf and Sc(OTf)3 ) by iron(III)-oxo complexes. Iron POU class 5 homeobox 1 Homo sapiens
2 The mechanisms of the oxidative C H bond cleavage of toluene derivatives, sulfoxidation of thioanisole derivatives, and epoxidation of styrene derivatives by mononuclear nonheme iron(IV)-oxo complexes in the presence of triflic acid (HOTf) and Sc(OTf)3 have been unified as rate-determining electron transfer coupled with binding of Lewis acids (HOTf and Sc(OTf)3 ) by iron(III)-oxo complexes. Iron POU class 5 homeobox 1 Homo sapiens