Title : Photoelectron-photofragment coincidence studies of the tert-butoxide anion (CH3)3CO((-)), the carbanion isomer (CH3)2CH2COH((-)), and corresponding radicals.

Pub. Date : 2014 Nov 6

PMID : 25289788






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1 Vibrationally resolved photoelectron spectra of stable radicals at 537 and 600 nm in conjunction with Franck-Condon simulations were used to assign the dominant channel to tert-butoxide ((CH(3)3)CO(-)) anions thermalized to a vibrational temperature of 550 K. DPD is assigned to highly vibrationally excited radicals produced by photodetachment of unrelaxed tert-butoxide products formed at an effective source temperature of 1400 K. The higher energy carbanion was found to be a minor channel and was not observed to dissociate. 2-methylpropan-2-olate dihydropyrimidine dehydrogenase Homo sapiens