Title : Conversion of (η(5)-C2B9H10R)TaX3 (X = Me, NMe2) to (η(6)-C2B9H10R)TaX' (X' = NMe2, azaallyl) in the absence of a reducing agent: synthesis and structure of tantallacarboranes incorporating an arachno-η(6)-C2B9(4-) ligand.

Pub. Date : 2014 Aug 4

PMID : 24939011






3 Functional Relationships(s)
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Compound Name
Protein Name
Organism
1 Heating a benzene solution of [eta(5)-(Me2NCH2CH2)C2B9H10] Ta(NMe2)3 (1) in the presence of pyridine gave an unprecedented complex [eta(1):eta(6)-(Me2NCH2CH2)C2B9H10]Ta (NMe2)(NC5H5) (2). pyridine endothelin receptor type A Homo sapiens
2 Heating a benzene solution of [eta(5)-(Me2NCH2CH2)C2B9H10] Ta(NMe2)3 (1) in the presence of pyridine gave an unprecedented complex [eta(1):eta(6)-(Me2NCH2CH2)C2B9H10]Ta (NMe2)(NC5H5) (2). pyridine endothelin receptor type A Homo sapiens
3 Heating a benzene solution of [eta(5)-(Me2NCH2CH2)C2B9H10] Ta(NMe2)3 (1) in the presence of pyridine gave an unprecedented complex [eta(1):eta(6)-(Me2NCH2CH2)C2B9H10]Ta (NMe2)(NC5H5) (2). pyridine endothelin receptor type A Homo sapiens