Title : Radical Reactivity of the Fe(III)/(II) Tetramesitylporphyrin Couple: Hydrogen Atom Transfer, Oxyl Radical Dissociation, and Catalytic Disproportionation of a Hydroxylamine.

Pub. Date : 2014 Jan

PMID : 24729854






1 Functional Relationships(s)
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1 The stable phenoxyl radical 2,4,6- t Bu3C6H2O (ArO ) forms a stronger bond to (TMP)FeII to irreversibly make a similar FeIII(OR) complex. tmp cytochrome P450 family 19 subfamily A member 1 Homo sapiens