Title : Infrared photodissociation spectroscopy of microhydrated nitrate-nitric acid clusters NO3(-)(HNO3)(m)(H2O)(n).

Pub. Date : 2014 Sep 4

PMID : 24666321






3 Functional Relationships(s)
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1 Infrared multiple photon dissociation (IRMPD) spectra of NO3(-)(HNO3)m(H2O)n(H2)z with m = 1-3, up to n = 8 and z >= 1, are measured in the fingerprint region (550-1880 cm(-1)), directly probing the NO-stretching modes, as well as bending and other lower frequency modes. Hydrogen NBL1, DAN family BMP antagonist Homo sapiens
2 Addition of at least one more nitric acid molecule or two more water molecules weakens the hydrogen bond network, breaking the symmetry of this arrangement and leading to localization of the proton near one of the nitrate cores, effectively forming HNO3 hydrogen-bonded to NO3(-). Hydrogen NBL1, DAN family BMP antagonist Homo sapiens
3 Addition of at least one more nitric acid molecule or two more water molecules weakens the hydrogen bond network, breaking the symmetry of this arrangement and leading to localization of the proton near one of the nitrate cores, effectively forming HNO3 hydrogen-bonded to NO3(-). Hydrogen NBL1, DAN family BMP antagonist Homo sapiens