Title : Isomerization of platinum-coordinated iminoethers induced by spectator ligands: stabilization of the Z anti configuration.

Pub. Date : 2013 Nov 18

PMID : 24187992






1 Functional Relationships(s)
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1 Upon investigation of the derivatives with L = PPh3, AsPh3, Me2S O, and (H2N)2C S, it has been concluded that an electrostatic interaction between the oxygen lone pair of the iminoether and the platinum center, fostered by the net positive charge of the complex and the low dielectric constant around the metal core provided by the hydrophobic L ligands, stabilizes the Z configuration. Platinum caveolin 1 Homo sapiens