Title : Mechanism and stereoselectivity of biologically important oxygenation reactions of the 7-dehydrocholesterol radical.

Pub. Date : 2013 Jul 19

PMID : 23829766






1 Functional Relationships(s)
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1 This insight derived through a detailed quantitative analysis of the stereocontrolling transition states suggests that the commonly found interpretations solely based on steric interactions between the incoming oxygen and the protruding angular methyl groups (C10, C13 methyls) in the beta face calls for adequate refinement. Oxygen homeobox C10 Homo sapiens