Title : Assembly and properties of heterobimetallic Co(II/III)/Ca(II) complexes with aquo and hydroxo ligands.

Pub. Date : 2012 Oct 24

PMID : 22998407






10 Functional Relationships(s)
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Protein Name
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1 The conversion of water to dioxygen in photosynthesis illustrates one example, in which a redox-inactive Ca(II) ion and four manganese ions are required for function. Water carbonic anhydrase 2 Homo sapiens
2 Water binds to [Co(II)MST](-) to form the five-coordinate [Co(II)MST(OH(2))](-) complex that was used to prepare the Co(II)/Ca(II) complex [Co(II)MST(mu-OH(2))Ca(II) 15-crown-5(OH(2))](+) ([Co(II)(mu-OH(2))Ca(II)OH(2)](+)). Water carbonic anhydrase 2 Homo sapiens
3 Water binds to [Co(II)MST](-) to form the five-coordinate [Co(II)MST(OH(2))](-) complex that was used to prepare the Co(II)/Ca(II) complex [Co(II)MST(mu-OH(2))Ca(II) 15-crown-5(OH(2))](+) ([Co(II)(mu-OH(2))Ca(II)OH(2)](+)). Water carbonic anhydrase 2 Homo sapiens
4 Water binds to [Co(II)MST](-) to form the five-coordinate [Co(II)MST(OH(2))](-) complex that was used to prepare the Co(II)/Ca(II) complex [Co(II)MST(mu-OH(2))Ca(II) 15-crown-5(OH(2))](+) ([Co(II)(mu-OH(2))Ca(II)OH(2)](+)). Water carbonic anhydrase 2 Homo sapiens
5 Water binds to [Co(II)MST](-) to form the five-coordinate [Co(II)MST(OH(2))](-) complex that was used to prepare the Co(II)/Ca(II) complex [Co(II)MST(mu-OH(2))Ca(II) 15-crown-5(OH(2))](+) ([Co(II)(mu-OH(2))Ca(II)OH(2)](+)). Water carbonic anhydrase 2 Homo sapiens
6 Water binds to [Co(II)MST](-) to form the five-coordinate [Co(II)MST(OH(2))](-) complex that was used to prepare the Co(II)/Ca(II) complex [Co(II)MST(mu-OH(2))Ca(II) 15-crown-5(OH(2))](+) ([Co(II)(mu-OH(2))Ca(II)OH(2)](+)). Water carbonic anhydrase 2 Homo sapiens
7 [Co(II)MST(OH(2))](-) was oxidized to form [Co(III)MST(OH(2))] that was further converted to [Co(III)MST(mu-OH)Ca(II) 15-crown-5](+) ([Co(III)(mu-OH)Ca(II)](+)) in the presence of base and Ca(II)OTf(2)/15-crown-5. Water carbonic anhydrase 2 Homo sapiens
8 [Co(II)MST(OH(2))](-) was oxidized to form [Co(III)MST(OH(2))] that was further converted to [Co(III)MST(mu-OH)Ca(II) 15-crown-5](+) ([Co(III)(mu-OH)Ca(II)](+)) in the presence of base and Ca(II)OTf(2)/15-crown-5. Water carbonic anhydrase 2 Homo sapiens
9 [Co(II)MST(OH(2))](-) was oxidized to form [Co(III)MST(OH(2))] that was further converted to [Co(III)MST(mu-OH)Ca(II) 15-crown-5](+) ([Co(III)(mu-OH)Ca(II)](+)) in the presence of base and Ca(II)OTf(2)/15-crown-5. Water carbonic anhydrase 2 Homo sapiens
10 [Co(II)MST(OH(2))](-) was oxidized to form [Co(III)MST(OH(2))] that was further converted to [Co(III)MST(mu-OH)Ca(II) 15-crown-5](+) ([Co(III)(mu-OH)Ca(II)](+)) in the presence of base and Ca(II)OTf(2)/15-crown-5. Water carbonic anhydrase 2 Homo sapiens