Title : Iron borohydride pincer complexes for the efficient hydrogenation of ketones under mild, base-free conditions: synthesis and mechanistic insight.

Pub. Date : 2012 Jun 4

PMID : 22532294






1 Functional Relationships(s)
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1 Concerted coordination of acetophenone and dual hydrogen-atom transfer from the PNP arm and the coordinated ethanol to, respectively, the carbonyl carbon and oxygen atoms, leads to the dearomatized complex [(iPr-PNP*)Fe(CO)(EtO)(MeCH(OH)Ph)] (32). Oxygen RUNX1 partner transcriptional co-repressor 1 Homo sapiens