Title : Unusually long, multicenter, cation(δ+)···anion(δ-) bonding observed for several polymorphs of [TTF][TCNE].

Pub. Date : 2011 Aug 16

PMID : 21793061






3 Functional Relationships(s)
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1 This reduced electrostatic interaction, and the large interfragment dispersion stabilize the long, heterocationic/anionic multicenter interaction, which in [TTF(delta+) TCNE(delta-)] always involves two electrons, but have ten, eight, and eight bond critical points (bcps) involving C-C, N-S, and sometimes C-S and C-N components for the alpha, beta, and delta polymorphs, respectively. Carbon ras homolog family member H Homo sapiens
2 This reduced electrostatic interaction, and the large interfragment dispersion stabilize the long, heterocationic/anionic multicenter interaction, which in [TTF(delta+) TCNE(delta-)] always involves two electrons, but have ten, eight, and eight bond critical points (bcps) involving C-C, N-S, and sometimes C-S and C-N components for the alpha, beta, and delta polymorphs, respectively. Carbon ras homolog family member H Homo sapiens
3 This reduced electrostatic interaction, and the large interfragment dispersion stabilize the long, heterocationic/anionic multicenter interaction, which in [TTF(delta+) TCNE(delta-)] always involves two electrons, but have ten, eight, and eight bond critical points (bcps) involving C-C, N-S, and sometimes C-S and C-N components for the alpha, beta, and delta polymorphs, respectively. Carbon ras homolog family member H Homo sapiens