Title : Ruthenium complexes with cooperative PNP-pincer amine, amido, imine, and enamido ligands: facile ligand backbone functionalization processes.

Pub. Date : 2010 Jun 21

PMID : 20486648






1 Functional Relationships(s)
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1 The distinctly different molecular and electronic structures of related complexes 1 and 3, which feature a Y-shaped distorted trigonal-bipyramid (Y-TBP) for amide 1 but T-shaped TBP for enamide 3, respectively, can be attributed to considerably reduced N-->M pi-donation for the PNP" ligand due to delocalization of the N-lone pair into the unsaturated pincer backbone. Amides TATA-box binding protein Homo sapiens