Title : Substitution reactions between bis-chelate ligands in palladium(II) alkenyl complexes: an unusual way to form unstable trans-P complexes. A study on the isomerization mechanism.

Pub. Date : 2009 Nov 21

PMID : 19859603






1 Functional Relationships(s)
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1 However, when the leaving group MeN-SPh and the entering ligand DPPQ are involved, the fast and quantitative substitution reaction leads to the formation of a couple of geometrical isomers [Pd(DPPQ)(Rx)Cl]-trans P and [Pd(DPPQ)(Rx)Cl]-cis P (Rx = Ra, Rb, Rc, Rd) in which the alkenyl and the phosphine groups are in mutual trans or cis position. pd(dppq) surfactant associated 3 Homo sapiens