Title : Enzyme-like acceleration for the hydrolysis of a DNA model promoted by a dinuclear Zn(II) catalyst in dilute aqueous ethanol.

Pub. Date : 2008 Oct 22

PMID : 18821763






1 Functional Relationships(s)
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1 Analysis of the kinetics of the reaction at 28 mM water indicates that second order rate constant for the catalytic reaction, given as kcatmax/Kd, is 4.6 x 104 M(-1) s(-1), is a factor of 8.4 x 10(10) larger than the second order rate constant (k2EtO) for the ethoxide promoted reaction of 2 in ethanol (5.5 +/- 0.3) x 10(-7) M(-1) s(-1). Water RUNX1 partner transcriptional co-repressor 1 Homo sapiens