Title : Solid state and solution structures of rhodium and iridium poly(pyrazolyl)borate diene complexes.

Pub. Date : 2008 May 28

PMID : 18688399






3 Functional Relationships(s)
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Sentence
Compound Name
Protein Name
Organism
1 For [Rh(eta-cod){B(pz)4}], [Rh(eta-dmbd)Tp"] (dmbd = 2,3-dimethylbuta-1,3-diene) and [Rh(eta-cod)Tp(Ph)] {Tp(Ph) = hydrotris(3-phenylpyrazolyl)borate} the fluxional process is slowed at low temperatures so that inequivalent pyrazolyl rings are observed. neotetrazolium endothelin receptor type A Homo sapiens
2 For [Rh(eta-cod){B(pz)4}], [Rh(eta-dmbd)Tp"] (dmbd = 2,3-dimethylbuta-1,3-diene) and [Rh(eta-cod)Tp(Ph)] {Tp(Ph) = hydrotris(3-phenylpyrazolyl)borate} the fluxional process is slowed at low temperatures so that inequivalent pyrazolyl rings are observed. neotetrazolium endothelin receptor type A Homo sapiens
3 Of the complexes with the more sterically hindered Tp(Ph) ligand, only [Rh(eta-nbd)Tp(Ph)] shows any degree of reversible oxidation. neotetrazolium endothelin receptor type A Homo sapiens