Title : Palladium-catalyzed three-component coupling of arynes with allylic acetates or halides and terminal alkynes promoted by cuprous iodide.

Pub. Date : 2008 May 14

PMID : 18438501






1 Functional Relationships(s)
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1 Benzynes react with allylic acetates or halides and terminal alkynes in the presence of Pd(PPh3)4, CuI and CsF in CH3CN at 50 degrees C for 5 h to give 1-allyl-2-alkynylbenzene derivatives in good to excellent yields. halides caveolin 1 Homo sapiens