Title : Reversibility effects on the stereoselectivity of Pt(II)-mediated cascade poly-ene cyclizations.

Pub. Date : 2008 Jan 16

PMID : 18095679






2 Functional Relationships(s)
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1 Cyclization of 1,5-dienes bearing nucleophilic traps with electrophilic trisphosphine pincer ligated Pt(II) complexes results in the formation of a polycyclic Pt-alkyl via a Pt(eta2-alkene) intermediate. Platinum DNA polymerase iota Homo sapiens
2 With electron-rich triphosphine ligands, an equilibrium between the Pt(eta2-alkene) and Pt-alkyl was observed. Platinum DNA polymerase iota Homo sapiens