Title : Infrared spectroscopy of prereactive aluminum-, gallium-, and indium-HCN entrance channel complexes solvated in helium nanodroplets.

Pub. Date : 2007 Dec 13

PMID : 17877336






3 Functional Relationships(s)
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1 Rotationally resolved infrared spectra are reported for the CH stretching vibration of the linear nitrogen-bound HCN-Ga and HCN-In complexes that show significant perturbation due to spin-orbit coupling of the 2Pi1/2 ground state with the 2Sigma1/2 state which are degenerate at long range. Nitrogen metastasis associated lung adenocarcinoma transcript 1 Homo sapiens
2 Rotationally resolved infrared spectra are reported for the CH stretching vibration of the linear nitrogen-bound HCN-Ga and HCN-In complexes that show significant perturbation due to spin-orbit coupling of the 2Pi1/2 ground state with the 2Sigma1/2 state which are degenerate at long range. Nitrogen metastasis associated lung adenocarcinoma transcript 1 Homo sapiens
3 A nitrogen-bound HCN-Al complex is not observed, which is attributed to reaction, even at 0.37 K. This conclusion is supported by the observation of a weakly bound complex containing two HCN"s and one Al atom which, from the analysis of its rotationally resolved zero-field and Stark spectra is assigned to a weakly bound complex of a HCNAl reaction product and a second HCN molecule. Nitrogen metastasis associated lung adenocarcinoma transcript 1 Homo sapiens