Title : Cleavage of carbon-carbon bonds of diphenylacetylene and its derivatives via photolysis of Pt complexes: tuning the C-C bond formation energy toward selective C-C bond activation.

Pub. Date : 2007 Jul 18

PMID : 17580867






1 Functional Relationships(s)
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1 Upon cleavage of the C-C bond in (dtbpe)Pt(eta2-(p-fluorophenyl-p-tolylacetylene) (9), both (dtbpe)Pt(p-fluorophenyl)(p-tolylacetylide) (10) and (dtbpe)Pt(p-tolyl)(p-fluorophenylacetylide) (11) were obtained. Platinum DNA polymerase iota Homo sapiens