Title : Collision-free photochemistry of methylazide: observation of unimolecular decomposition of singlet methylnitrene.

Pub. Date : 2006 Oct 7

PMID : 17029455






1 Functional Relationships(s)
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1 We explain our observations through a mechanism which is initiated by the isomerization of 1CH3N to a highly internally excited methanimine H2C=NH isomer, which decomposes by 1,1-H2 elimination forming HNC+H2 as well as sequential H-atom loss (N-H followed by C-H bond cleavage), to form HCN. Hydrogen metastasis associated lung adenocarcinoma transcript 1 Homo sapiens