Title : Mutual sensitization of the oxidation of nitric oxide and a natural gas blend in a JSR at elevated pressure: experimental and detailed kinetic modeling study.

Pub. Date : 2006 Jun 1

PMID : 16722672






4 Functional Relationships(s)
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1 According to the proposed kinetic scheme, the mutual sensitization of the oxidation of this natural gas blend and NO proceeds through the NO to NO2 conversion by HO2, CH3O2, and C2H5O2. Nitrogen Dioxide heme oxygenase 2 Homo sapiens
2 820 K) than at higher temperatures where the reaction of NO with HO2 controls the NO to NO2 conversion. Nitrogen Dioxide heme oxygenase 2 Homo sapiens
3 A simplified reaction scheme was delineated: NO + HO2 --> NO2 + OH followed by OH + CH4 --> CH3 + H2O and OH + C2H6 --> C2H5 + H2O. Nitrogen Dioxide heme oxygenase 2 Homo sapiens
4 The kinetic analyses indicate that in the NO-seeded conditions, the main production of OH proceeds via the same route, NO + HO2 --> NO2 + OH. Nitrogen Dioxide heme oxygenase 2 Homo sapiens