Title : Synthesis, structure, and reactivity of a eta(3)-1-hydroxyallyl complex: protonation of an alpha,beta-unsaturated carbonyl compound bound to palladium(0) and platinum(0).

Pub. Date : 2003 Jul 30

PMID : 15369351






2 Functional Relationships(s)
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1 The direct addition of a proton to a carbonyl oxygen in an eta2-enone complex of palladium and platinum led to the quantitative formation of eta3-1-hydroxyallyl complexes of palladium and platinum, of which X-ray diffraction analysis showed typical eta3-allyl structure. Platinum DNA polymerase iota Homo sapiens
2 The direct addition of a proton to a carbonyl oxygen in an eta2-enone complex of palladium and platinum led to the quantitative formation of eta3-1-hydroxyallyl complexes of palladium and platinum, of which X-ray diffraction analysis showed typical eta3-allyl structure. Platinum DNA polymerase iota Homo sapiens