Title : Diastereomeric Control in the Formation of Carbon-Cobalt Bonds in Organocobalt Corrinoids: Reactions of Cobalt(II) Corrinoids with Organic Hydroperoxides(1).

Pub. Date : 1997 Apr 23

PMID : 11669778






1 Functional Relationships(s)
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1 For cob(II)inamide itself, the alpha diastereomer is enthalpically stabilized relative to the beta diastereomer in the transition state for carbon-cobalt bond formation, but an even larger entropic stabilization of the beta diastereomer causes the latter to be the predominant product. Cobalt metabolism of cobalamin associated B Homo sapiens