Title : Kinetic and mechanistic study with optically active, four-coordinate nickel(II) complexes: stereoselectivity in ligand substitution.

Pub. Date : 2000 Oct 30

PMID : 11233209






1 Functional Relationships(s)
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1 The ratio of second-order rate constants, kfast/kslow, with kfast being rate constant k for the faster reacting pair of enantiomers and vice versa, lies in the range 1.0-3.0, depending on the nature of the N-alkyl groups in NiA2 and organic groups attached to the ethylene bridge in the salen ligands H2B. ethylene H2B clustered histone 21 Homo sapiens