Title : Diastereoselectivity an chiral ruthenium complexes of chiraphos monoxide ligands: epimerization, quasiracemates, and Lewis acid catalysis.

Pub. Date : 2000 Jun

PMID : 10824147






1 Functional Relationships(s)
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1 The doubly charged Lewis acid, [CyRu(eta2-(R, R)-Ph2PCHMeCHMe Ph2PO-P,O)(solvate)]2+ derived from the chloro complex by chloride abstraction with AgSbF6 gave modest ee"s (30%) in the Diels-Alder reaction of methacrolein with cyclopentadiene. Cyclopentanes DNA polymerase iota Homo sapiens