Title : Bimetallic system for nitrogen fixation: ruthenium-assisted protonation of coordinated N2 on tungsten with H2

Pub. Date : 1998 Jan 23

PMID : 9438842






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1 Bimetallic system for nitrogen fixation: ruthenium-assisted protonation of coordinated N2 on tungsten with H2 Treatment of the tungsten dinitrogen complex cis-[W(N2)2(PMe2Ph)4] (Me = methyl, Ph = phenyl) with an equilibrium mixture of [RuCl(dppp)2]X and trans-[RuCl(eta2-H2)(dppp)2]X [X = BF4, PF6, or OSO2CF3; dppp = 1,3-bis(diphenylphosphino)propane] under 1 atmosphere of dihydrogen at 55 degrees Celsius for 24 hours gave NH3 in moderate yield. Tungsten sperm associated antigen 17 Homo sapiens