Title : Conformational dependence of electron transfer across de novo designed metalloproteins.

Pub. Date : 1996 Sep 3

PMID : 8790363






1 Functional Relationships(s)
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1 Flash photolysis and pulse radiolysis measurements demonstrate a conformational dependence of electron transfer rates across a 16-mer helical bundle (three-helix metalloprotein) modified with a capping CoIII(bipyridine)3 electron acceptor at the N terminus and a 1-ethyl-1"-ethyl-4,4"- bipyridinium donor at the C terminus. 1-ethyl-1"-ethyl-4,4"- bipyridinium mitochondrially encoded cytochrome c oxidase III Homo sapiens