Title : Hydrogen bond, ring tension and π-conjugation effects: methyl and vinyl substitutions dramatically change the photodynamics of Criegee intermediates.

Pub. Date : 2020 Jul 21

PMID : 32618986






1 Functional Relationships(s)
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1 In addition, the CHO hydrogen bond in the syn(CO)-VCI further stabilizes the S1-state intermediates and makes them less reactive; in contrast, isomerization to dioxirane becomes the globally dominant channel in the anti(CO)-VCI. dioxirane synemin Homo sapiens