Title : On Silylated Oxonium and Sulfonium Ions and Their Interaction with Weakly Coordinating Borate Anions.

Pub. Date : 2020 Feb 3

PMID : 31738450






2 Functional Relationships(s)
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1 In the reaction of Me3Si-O-SiMe3 with [Me3Si-H-SiMe3][B(C6F5)4], a ligand exchange was observed in the [Me3Si-H-SiMe3]+ cation leading to the surprising formation of the persilylated [(Me3Si)2(Me2(H)Si)O]+ oxonium ion in a formal [Me2(H)Si]+ instead of the desired [Me3Si]+ transfer reaction. hydronium ion malic enzyme 2 Homo sapiens
2 In the reaction of Me3Si-O-SiMe3 with [Me3Si-H-SiMe3][B(C6F5)4], a ligand exchange was observed in the [Me3Si-H-SiMe3]+ cation leading to the surprising formation of the persilylated [(Me3Si)2(Me2(H)Si)O]+ oxonium ion in a formal [Me2(H)Si]+ instead of the desired [Me3Si]+ transfer reaction. hydronium ion malic enzyme 2 Homo sapiens