Title : Facile and systematic access to the least-coordinating WCA [(RFO)3Al-F-Al(ORF)3]- and its more Lewis-basic brother [F-Al(ORF)3]- (RF = C(CF3)3).

Pub. Date : 2018 Sep 21

PMID : 30310626






11 Functional Relationships(s)
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Protein Name
Organism
1 By reaction of the Lewis acid Me3Si-F-Al(ORF)3 with a series of [PF6]- salts, gaseous PF5 and Me3Si-F are liberated and salts of the anion [F-Al(ORF)3]- ([f-al]-; RF = C(CF3)3) can be obtained. PHOSPHORUS PENTAFLUORIDE ankyrin repeat, SAM and basic leucine zipper domain containing 1 Homo sapiens
2 By reaction of the Lewis acid Me3Si-F-Al(ORF)3 with a series of [PF6]- salts, gaseous PF5 and Me3Si-F are liberated and salts of the anion [F-Al(ORF)3]- ([f-al]-; RF = C(CF3)3) can be obtained. PHOSPHORUS PENTAFLUORIDE ankyrin repeat, SAM and basic leucine zipper domain containing 1 Homo sapiens
3 By reaction of the Lewis acid Me3Si-F-Al(ORF)3 with a series of [PF6]- salts, gaseous PF5 and Me3Si-F are liberated and salts of the anion [F-Al(ORF)3]- ([f-al]-; RF = C(CF3)3) can be obtained. me3si-f ankyrin repeat, SAM and basic leucine zipper domain containing 1 Homo sapiens
4 By addition of another equivalent of Me3Si-F-Al(ORF)3 to [f-al]-, gaseous Me3Si-F is released and salts of the least coordinating anion [(RFO)3Al-F-Al(ORF)3]- ([al-f-al]-) are formed. f-al ankyrin repeat, SAM and basic leucine zipper domain containing 1 Homo sapiens
5 By addition of another equivalent of Me3Si-F-Al(ORF)3 to [f-al]-, gaseous Me3Si-F is released and salts of the least coordinating anion [(RFO)3Al-F-Al(ORF)3]- ([al-f-al]-) are formed. f-al ankyrin repeat, SAM and basic leucine zipper domain containing 1 Homo sapiens
6 By addition of another equivalent of Me3Si-F-Al(ORF)3 to [f-al]-, gaseous Me3Si-F is released and salts of the least coordinating anion [(RFO)3Al-F-Al(ORF)3]- ([al-f-al]-) are formed. me3si-f ankyrin repeat, SAM and basic leucine zipper domain containing 1 Homo sapiens
7 By addition of another equivalent of Me3Si-F-Al(ORF)3 to [f-al]-, gaseous Me3Si-F is released and salts of the least coordinating anion [(RFO)3Al-F-Al(ORF)3]- ([al-f-al]-) are formed. Aluminum ankyrin repeat, SAM and basic leucine zipper domain containing 1 Homo sapiens
8 By addition of another equivalent of Me3Si-F-Al(ORF)3 to [f-al]-, gaseous Me3Si-F is released and salts of the least coordinating anion [(RFO)3Al-F-Al(ORF)3]- ([al-f-al]-) are formed. Aluminum ankyrin repeat, SAM and basic leucine zipper domain containing 1 Homo sapiens
9 Thus, it is similarly Lewis acidic as BF3 and eventually reacts with nucleophiles (Nu) from the reaction environment to yield Nu-Al(ORF)3 and [f-al]-. nu-al ankyrin repeat, SAM and basic leucine zipper domain containing 1 Homo sapiens
10 Subsequently it may be transformed into the [al-f-al]- salt by simple addition of one equivalent of Me3Si-F-Al(ORF)3. al-f-al]- salt ankyrin repeat, SAM and basic leucine zipper domain containing 1 Homo sapiens
11 Subsequently it may be transformed into the [al-f-al]- salt by simple addition of one equivalent of Me3Si-F-Al(ORF)3. me3si-f-al ankyrin repeat, SAM and basic leucine zipper domain containing 1 Homo sapiens