Title : Cyclopentanoids from cyclopentadiene: synthesis of (-)-methyl jasmonate and (+)-12-oxophytodienoic acid.

Pub. Date : 2013 Jul

PMID : 23980424






1 Functional Relationships(s)
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1 The alpha-chain was introduced to the cyclopentane ring via the S(N)2 type nucleophilic substitution of (1S,2R,3R,2"Z)-3-acetoxy-2-(pent-2"-enyl)cyclopent-4-ene-1-ol with a dialkylcuprate for (+)-12-oxo-PDA. 12-oxophytodienoic acid Fc gamma receptor and transporter Homo sapiens