Title : Novel tailoring reaction for two adjacent coordinated nitriles giving platinum 1,3,5-triazapentadiene complexes.

Pub. Date : 2008 Dec 15

PMID : 18376821






1 Functional Relationships(s)
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1 When any of the trans-[PtCl(2)(RCN)(2)] (R = Et, CH(2)Ph, Ph) complexes reacts in the corresponding nitrile RCN with 4 equiv of DPG at prolonged reaction time (75 degrees C, 1-2 days), complexes containing two bidentate 1,3,5-triazapentadiene ligands, i.e. [Pt{NH=C(R)NC(NHPh)=NPh}(2)] (14-16), are formed. 1,3,5-triazapentadiene reticulocalbin 1 Homo sapiens