Title : Concise syntheses of tridentate PNE ligands and their coordination chemistry with palladium(II) : a solution- and solid-state study.

Pub. Date : 2006 Sep 14

PMID : 16924291






4 Functional Relationships(s)
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1 Reaction of the functionalised tertiary phosphines 1-3 with PdCl2(MeCN)2 affords complexes in which the ligands are bound in a tridentate fashion, namely [PdCl(kappa3-PNE)]Cl (6a, 8) as the predominant products. Phosphines phosducin like 2 Homo sapiens
2 Reaction of the functionalised tertiary phosphines 1-3 with PdCl2(MeCN)2 affords complexes in which the ligands are bound in a tridentate fashion, namely [PdCl(kappa3-PNE)]Cl (6a, 8) as the predominant products. pdcl(kappa3-pne)]cl phosducin like 2 Homo sapiens
3 A kappa2-PN coordination mode was also identified crystallographically for ligand following its reaction with PdCl2(MeCN)2, which afforded [PdCl2(-kappa2-PN)] (6b) in ca. kappa2-pn phosducin like 2 Homo sapiens
4 A kappa2-PN coordination mode was also identified crystallographically for ligand following its reaction with PdCl2(MeCN)2, which afforded [PdCl2(-kappa2-PN)] (6b) in ca. pdcl2(-kappa2-pn) phosducin like 2 Homo sapiens