Title : A ring walk of methylene groups in toluene radical cations. An extension of the toluene-cycloheptatriene rearrangement of aromatic radical cations. Theory and experiment.

Pub. Date : 2003

PMID : 12939485






4 Functional Relationships(s)
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1 This ring walk corresponds to interconversion of distonic ions and norcaradiene radical cations (the two intermediates of the TOL/CHT-rearrangement) by making and breaking of the external C-C bonds of the cyclopropane moiety of the intermediate norcaradiene structure. bicyclo(4.1.0)hepta-2,4-diene solute carrier family 5 member 7 Homo sapiens
2 This ring walk corresponds to interconversion of distonic ions and norcaradiene radical cations (the two intermediates of the TOL/CHT-rearrangement) by making and breaking of the external C-C bonds of the cyclopropane moiety of the intermediate norcaradiene structure. cyclopropane solute carrier family 5 member 7 Homo sapiens
3 This ring walk corresponds to interconversion of distonic ions and norcaradiene radical cations (the two intermediates of the TOL/CHT-rearrangement) by making and breaking of the external C-C bonds of the cyclopropane moiety of the intermediate norcaradiene structure. bicyclo(4.1.0)hepta-2,4-diene solute carrier family 5 member 7 Homo sapiens
4 The calculation was repeated for the MERPs of a TOL/CHT-rearrangement of para-xylene radical cation 5 and ethylbenzene radical cation 2, yielding basically the same results as for 1. 4-xylene solute carrier family 5 member 7 Homo sapiens