Title : Reactions of Tri-tert-Butylphosphatetrahedrane as a Spring-Loaded Phosphinidene Synthon Featuring Nickel-Catalyzed Transfer to Unactivated Alkenes.

Pub. Date : 2022 May 4

PMID : 35437987






1 Functional Relationships(s)
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1 Treatment of the ethylene-derived phosphirane product with triflic acid delivered elimination of (tBu3C3)OTf and formation of a P-H bond, illustrating the ability of the tri-tert-butyl cyclopropenyl group to serve as a protecting group that is removable following phosphinidene transfer. ethylene tRNA-Ile (anticodon AAT) 9-1 Homo sapiens