Title : A New Paradigm in Enantioselective Cobalt Catalysis: Cationic Cobalt(I) Catalysts for Heterodimerization, Cycloaddition, and Hydrofunctionalization Reactions of Olefins.

Pub. Date : 2021 Dec 21

PMID : 34847327






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1 Through an approach that relies on mechanistic insights and systematic examination of ligand and counterion effects, we developed an efficient cobalt-based catalytic system ((P~P)CoX2/Me3Al) (P~P = bisphosphine) to effect the first enantioselective heterodimerization of several types of 1,3-dienes with ethylene. Cobalt mitochondrially encoded cytochrome c oxidase II Homo sapiens