Title : Solvent and Temperature Effects on Photoinduced Proton-Coupled Electron Transfer in the Marcus Inverted Region.

Pub. Date : 2021 Sep 9

PMID : 34432465






1 Functional Relationships(s)
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1 Nonpolar solvents decrease both DeltaG CR and lambda, slowing CR into the nanosecond time regime for 2 in toluene at 298 K. This demonstrates how PCET in the inverted region may be controlled to potentially use proton-coupled CS states for efficient solar fuel production and photoredox catalysis. Toluene citrate synthase Homo sapiens