Title : Dimerization and Cycloaddition Reactions of Transient Tri-tert-butylphosphacyclobutadiene Generated by Lewis Acid Induced Isomerization of Tri-tert-butylphosphatetrahedrane.

Pub. Date : 2021 Aug 25

PMID : 34380311






1 Functional Relationships(s)
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1 Trapping of a generated intermediate was achieved by repeating the experiment in the presence of excess styrene (20 equiv) or ethylene (1 atm), and the corresponding (4 + 2) cycloadducts of tri-tert-butylphosphacyclobutadiene were isolated in 88% and 74% yields, respectively. ethylene tRNA-Ile (anticodon AAT) 9-1 Homo sapiens