Title : Ferrate self-decomposition in water is also a self-activation process: Role of Fe(V) species and enhancement with Fe(III) in methyl phenyl sulfoxide oxidation by excess ferrate.

Pub. Date : 2021 Jun 1

PMID : 33836297






4 Functional Relationships(s)
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1 This ferrate dosage effect was diminished greatly in the condition of excess PMSO where ferrate self-decomposition was lessened largely, or counterbalanced by adding a strong complexing ligand (e.g. pyrophosphate) to sequester Fe(V) oxidation, demonstrating that the Fe(V) species derived from ferrate self-decomposition plays an important role in PMSO oxidation. pmso FEV transcription factor, ETS family member Homo sapiens
2 This ferrate dosage effect was diminished greatly in the condition of excess PMSO where ferrate self-decomposition was lessened largely, or counterbalanced by adding a strong complexing ligand (e.g. pyrophosphate) to sequester Fe(V) oxidation, demonstrating that the Fe(V) species derived from ferrate self-decomposition plays an important role in PMSO oxidation. pmso FEV transcription factor, ETS family member Homo sapiens
3 A mechanistic kinetics model involving the ferrate self-decomposition and PMSO oxidation by Fe(VI), Fe(V) and Fe(IV) species was then developed and validated. pmso FEV transcription factor, ETS family member Homo sapiens
4 The modeling results show that up to 99% of the PMSO oxidation was contributed by the ferrate self-decomposition resultant Fe(V) species in borate buffer, revealing that ferrate self-decomposition is also a self-activation process. pmso FEV transcription factor, ETS family member Homo sapiens